Anodic Oxidation of N-Substituted Dipyrrolyl Linked by Polyether Bridge

No Thumbnail Available

Date

2006

Authors

Journal Title

Journal ISSN

Volume Title

Publisher

Taylor & Francis inc

Open Access Color

OpenAIRE Downloads

OpenAIRE Views

Research Projects

Organizational Units

Thumbnail Image
Organizational Unit
Chemical Engineering
(2010)
Established in 2010, and aiming to train the students with the capacity to meet the demands of the 21st Century, the Chemical Engineering Department provides a sound chemistry background through intense coursework and laboratory practices, along with fundamental courses such as Physics and Mathematics within the freshman and sophomore years, following preparatory English courses.In the final two years of the program, engineering courses are offered with laboratory practice and state-of-the-art simulation programs, combining theory with practice.

Journal Issue

Events

Abstract

Electroactive polymer containing polyether pseudo-cages has been synthesized by anodic oxidation of 1,11-bis(1,1-pyrrole)-3,6,9-trioxaundecane (I) using acetonitrile (ACN) as solvent and tetrabutylammonium perchlorate (TBAClO 4 ) as supporting electrolyte. Electrochemical behavior of monomer I and its polymer, poly-I , were studied using cyclic voltammetry (CV) and UV-VIS spectroscopic techniques. Also, a doping/dedoping study was carried out using electron spin resonance (ESR) and UV-VIS spectroscopic techniques. Thermal behavior of the product was studied using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA).

Description

Keywords

electrochemical polymerization, N-substituted dipyrrolyl

Turkish CoHE Thesis Center URL

Fields of Science

Citation

WoS Q

Scopus Q

Q2

Source

Volume

43

Issue

9

Start Page

1379

End Page

1386

URI

https://doi.org/10.1080/10601320600815074
 https://hdl.handle.net/20.500.14411/1188

Collections

WOS
Scopus