Browsing by Author "Caglayan, Dilara Gulcin"

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Citation - WoS: 87
Citation - Scopus: 105
Modeling and Sensitivity Analysis of High Temperature Pem Fuel Cells by Using Comsol Multiphysics
(Pergamon-elsevier Science Ltd, 2016) Sezgin, Berna; Caglayan, Dilara Gulcin; Devrim, Yilser; Steenberg, Thomas; Eroglu, Inci; Energy Systems Engineering; 06. School Of Engineering; 01. Atılım University
The objective of this study is to observe the effect of the critical design parameters, velocities of inlet gases (hydrogen and air) and the conductivity of polymer membrane, on the performance of a high temperature PEM fuel cell. A consistent and systematic mathematical model is developed in order to study the effect of these parameters. The model is applied to an isothermal, steady state, three-dimensional PEM fuel cell in order to observe concentration profiles, current density profiles and polarization curves. The model includes the transport of gases in anode and cathode gas flow channels, diffusion in the catalyst layers, the transport of water and hydronium ion in the polymer electrolyte and in the catalyst layers, and the transport of electrical current in the solid phase. The model is considered as having a single flow channel. The simulation is performed by using licensed Comsol Multiphysics 5.0, Fuel Cells &Batteries Module. The results compare well with the experimental polarization data obtained at 160 degrees C for ohmic and activation regions. The best match with the experimental data is obtained when the inlet hydrogen gas velocity is 0.133 m/s whereas inlet air velocity is 1.3 m/s for proton conductivity of 10 S/m. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
Citation - WoS: 42
Citation - Scopus: 55
Three-Dimensional Modeling of a High Temperature Polymer Electrolyte Membrane Fuel Cell at Different Operation Temperatures
(Pergamon-elsevier Science Ltd, 2016) Caglayan, Dilara Gulcin; Sezgin, Berna; Devrim, Yilser; Eroglu, Inci; Energy Systems Engineering; 06. School Of Engineering; 01. Atılım University
A three-dimensional model for a high temperature polymer electrolyte membrane (PEM) fuel cell having an active area of 25 cm(2) is developed. Triple mixed serpentine flow channel single cell with phosphoric acid doped polybenzimidazole (FBI) membrane is used in the model. Steady-state, isothermal, single phase assumptions are defined for the system. The model is simulated at different temperatures ranging from 100 to 180 degrees C to investigate the influence of operation temperature on the performance of the cell. It is seen that there is an improvement in the performance of the cell as the operation temperature increases. Experimental data are used to validate the model both for single channel and triple mixed serpentine flow channel. Current density distribution is obtained at different operating voltages. The predicted results show that at high operating voltages the local current density is almost uniform; whereas, decreasing operating voltage causes non-uniformities in the local current density. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
Citation - WoS: 17
Citation - Scopus: 20
Three-Dimensional Non-Isothermal Model Development of High Temperature Pem Fuel Cells
(Pergamon-elsevier Science Ltd, 2018) Caglayan, Dilara Gulcin; Sezgin, Berna; Devrim, Yilser; Eroglu, Inci; Energy Systems Engineering; 06. School Of Engineering; 01. Atılım University
A three-dimensional non-isothermal mathematical model is developed in a triple mixed serpentine flow multichannel domain for a high temperature PEM Fuel Cell having a phosphoric acid doped PBI membrane as electrolyte and an active area of 25 cm(2) within Comsol Multiphysics. The inlet temperatures of cathode and anode reactants are taken as 438 K. Model predicts pressure, and temperature distribution along the channels and membrane current density distribution over the membrane electrodes. The model results are obtained at two different operation voltages, 0.45 V and 0.60 V. Resulting average current densities are respectively 0.313 A cm(-2) and 0.224 A cm(-2). The non-isothermal model results are compared to isothermal model results from a previous study and various other single channel non-isothermal model results available in the literature. The pressure drop at cathode compartment is predicted to be 6500 Pa, whereas it is found to be 6400 Pa for the isothermal model. The temperature difference within the system is found to be 0.18 K for the operation voltage of 0.6 V, whereas this value increases to 0.31 K for the operation voltage of 0.45 V. The temperature difference isocontours are illustrated for the whole cell. Considering changes in temperature, one can employ isothermal operation assumption for this system as an approximation and simplification for the governing equations, since the variation in the temperature within the cell is less than 1 K. It should be emphasized that multichannel model predictions are more realistic compared to single channel models. The model developed here can be extended to larger electrode active area and different multichannel configurations. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.