ELECTROCHEMICAL HYDROGEN SEPARATION FROM REFORMATE USING POLYBENZIMIDAZOLE/MOF COMPOSITE MEMBRANES

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2022

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International Association for Hydrogen Energy, IAHE

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Mechanical Engineering
(2009)
The Atılım University Department of Mechanical Engineering started education in 2009, and offers graduate and doctorate degree programs, in addition to its undergraduate program. Our main goal is to graduate Mechanical Engineers who have the skills to design, analyze and synthesize; who are able to convert advanced technology and innovations into products; and who have the culture of research and cooperation. While our graduates reach this goal, they adopt the principle of life-long learning, and develop a sense of entrepreneurship, paying importance to professional ethics. With a curriculum prepared in line with the criteria of MÜDEK, we help our students develop themselves professionally, and socially. Graduates of mechanical engineering may be employed in many sectors and in a wide array of positions. Able to work under any field that involves production and energy conversion, graduates of the department may also gain expertise in fields such as aviation, automotive, or material engineering.
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Energy Systems Engineering
(2009)
The Department of Energy Systems Engineering admitted its first students and started education in the academic year of 2009-2010 under Atılım University School of Engineering. In this Department, all kinds of energy are presented in modules (conventional energy, renewable energy, hydrogen energy, bio-energy, nuclear energy, energy planning and management) from their detection, production and procession; to their transfer and distribution. A need is to arise for a surge of energy systems engineers to ensure energy supply security and solve environmental issues as the most important problems of the fifty years to come. In addition, Energy Systems Engineering is becoming among the most important professions required in our country and worldwide, especially within the framework of the European Union harmonization process, and within the free market economy.

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Abstract

This study introduces the experimental results of a high-temperature electrochemical hydrogen purification (ECHP) cell through poly 2.2-m-phenylene-5.5-bibenzimidazole/metal organic framework (PBI/MOF) composite membranes in the temperature range of 140°C-180°C. Synthesis of ZIF-8 and UiO-66 MOFs was conducted through a typical solvothermal method, and composite membranes containing 2.5 wt. %. MOF was fabricated. Experiments were conducted with pure hydrogen (H2) and reformate gas mixtures containing H2, carbon monoxide (CO), and carbon dioxide (CO2). A gas chromatography device (GC) was used to analyze the gas composition at the exit of the ECHP cell. The final output H2 purity was found to be >99.9 % for the H2/CO2/CO mixed-phase and >99.7% for the H2/CO mixed phase. © 2022 Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2. All rights reserved.

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BAU; et al.; INOGEN; Republic of Turkey, Ministry of Energy and Natural Resources; TENMARK; Turkish Airlines

Keywords

Electrochemical hydrogen separation, Metal-organic framework, UIO-66, ZIF-8

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Proceedings of WHEC 2022 - 23rd World Hydrogen Energy Conference: Bridging Continents by H2 -- 23rd World Hydrogen Energy Conference: Bridging Continents by H2, WHEC 2022 -- 26 June 2022 through 30 June 2022 -- Istanbul -- 186176

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Start Page

403

End Page

405

URI

https://hdl.handle.net/20.500.14411/9557

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Scopus