Uzundurukan, ArifeDevrim, YilserEnergy Systems Engineering2024-07-052024-07-0520190360-31991879-348710.1016/j.ijhydene.2019.04.1882-s2.0-85065584145https://doi.org/10.1016/j.ijhydene.2019.04.188https://hdl.handle.net/20.500.14411/3297DEVRIM, YILSER/0000-0001-8430-0702; UZUNDURUKAN, ARIFE/0000-0003-1104-1644In this study, it is aimed to investigate hydrogen (H-2) generation from sodium borohydride (NaBH4) hydrolysis by multi-walled carbon nanotube supported platinum catalyst (Pt/MWCNT) under various conditions (0-0.03 g Pt amount catalyst, 2.58-5.03 wt % NaBH4, and 27-67 degrees C) in detail. For comparison, carbon supported platinum (Pt/C) commercial catalyst was used for H-2 generation experiments under the same conditions. The reaction rate of the experiments was described by a power law model which depends on the temperature of the reaction and concentrations of NaBH4. Kinetic studies of both Pt/MWCNT and Pt/C catalysts were done and activation energies, which is the required minimum energy to overcome the energy barrier, were found as 27 kJ/mol and 36 kJ/mol, respectively. Pt/ MWCNT catalyst is accelerated the reaction less than Pt/C catalyst while Pt/MWCNT is more efficient than Pt/C catalyst, they are approximately 98% and 95%, respectively. According to the results of experiments and the kinetic study, the reaction system based on NaBH4 in the presence of Pt/MWCNT catalyst can be a potential hydrogen generation system for portable applications of proton exchange membrane fuel cell (PEMFC). (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.eninfo:eu-repo/semantics/closedAccessHydrogen generationSodium borohydrideHydrolysisCatalystPt/MWCNTArticleQ144331758617594WOS:00047696490001544