Electrochemical and Optical Properties of New Soluble Dithienylpyrroles Based on Azo Dyes

No Thumbnail Available

Date

2009

Authors

Cihaner, Atilla
Cihaner, Atilla
Algi, Fatih

Journal Title

Journal ISSN

Volume Title

Publisher

Pergamon-elsevier Science Ltd

Open Access Color

OpenAIRE Downloads

OpenAIRE Views

Research Projects

Organizational Units

Organizational Unit
Chemical Engineering
(2010)
Established in 2010, and aiming to train the students with the capacity to meet the demands of the 21st Century, the Chemical Engineering Department provides a sound chemistry background through intense coursework and laboratory practices, along with fundamental courses such as Physics and Mathematics within the freshman and sophomore years, following preparatory English courses.In the final two years of the program, engineering courses are offered with laboratory practice and state-of-the-art simulation programs, combining theory with practice.

Journal Issue

Abstract

Two dithienylpyrroles based on azo dyes, namely 2,5'-dimethyl-[4-(2,5-di-thiophen-2-yl-pyrrol-1-yl)-phenyl]azobenzene (SNS-AB2) and 2,5'- dimethyloxy-[4-(2,5-di-thiophen-2-yl-pyrrol-1-yl)phenyl]azobenzene (SNS-AB3), were synthesized and their corresponding polymers (PSNS-AB2 and PSNS-AB3) were successfully obtained via electropolymerization. The monomers have lower oxidation potentials (0.75 V and 0.80V vs. Ag/AgCl for SNS-AB2 and SNS-AB3, respectively) when compared to their analogous. Both monomers exhibited photoisomerism properties under irradiation at 360 nm. During the irradiation process, for example, the color of SNS-AB3 changes from yellow to greenish yellow. The electroactive polymer films have well defined and reversible redox couples with a good cycle stability in both aqueous and organic solutions. The polymer films also exhibited electrochromic behaviors; color changes from yellowish green to dark green for the PSNS-AB2 (lambda(max) = 435 nm and E-g = 2.31 eV) and from mustard color to green for PSNS-AB3 (lambda(max) = 430nm and E-g = 2.34 eV). Furthermore, the soluble polymers demonstrated different hues of yellow and green colors. (C) 2008 Elsevier Ltd. All rights reserved.

Description

Algi, Fatih/0000-0001-9376-1770

Keywords

Electropolymerization, Photoisomerization, Polythiophene, Polypyrrole, Azobenzene

Turkish CoHE Thesis Center URL

Fields of Science

Citation

41

WoS Q

Q2

Scopus Q

Source

Volume

54

Issue

6

Start Page

1702

End Page

1709

Collections