Further Development of Polyepichlorohydrin Based Anion Exchange Membranes for Reverse Electrodialysis by Tuning Cast Solution Properties

dc.authorid Güler, Enver/0000-0001-9175-0920
dc.authorid Altıok, Esra/0000-0001-5229-4766
dc.authorid Ortiz, Inmaculada/0000-0002-3257-4821
dc.authorid Cihanoglu, Aydin/0000-0003-3401-2416
dc.authorscopusid 57566296100
dc.authorscopusid 56413071900
dc.authorscopusid 35795160600
dc.authorscopusid 56200883200
dc.authorscopusid 57204055541
dc.authorscopusid 6602100613
dc.authorscopusid 7006312029
dc.authorwosid Cihanoğlu, Aydın/IQW-7599-2023
dc.authorwosid Güler, Enver/C-1589-2015
dc.authorwosid Altıok, Esra/HMD-3542-2023
dc.authorwosid Ortiz, Inmaculada/K-8570-2014
dc.contributor.author Eti, Mine
dc.contributor.author Cihanoglu, Aydin
dc.contributor.author Guler, Enver
dc.contributor.author Gomez-Coma, Lucia
dc.contributor.author Altiok, Esra
dc.contributor.author Arda, Muserref
dc.contributor.author Kabay, Nalan
dc.contributor.other Chemical Engineering
dc.date.accessioned 2024-07-05T15:24:17Z
dc.date.available 2024-07-05T15:24:17Z
dc.date.issued 2022
dc.department Atılım University en_US
dc.department-temp [Eti, Mine; Cihanoglu, Aydin; Altiok, Esra; Kabay, Nalan] Ege Univ, Fac Engn, Dept Chem Engn, TR-35100 Izmir, Turkey; [Guler, Enver] Atilim Univ, Dept Chem Engn, TR-06830 Ankara, Turkey; [Gomez-Coma, Lucia; Ortiz, Inmaculada] Univ Cantabria, Dept Chem & Biomol Engn, Av Castros 46, Santander 39005, Spain; [Arda, Muserref] Ege Univ, Fac Sci, Dept Chem, TR-35100 Izmir, Turkey en_US
dc.description Güler, Enver/0000-0001-9175-0920; Altıok, Esra/0000-0001-5229-4766; Ortiz, Inmaculada/0000-0002-3257-4821; Cihanoglu, Aydin/0000-0003-3401-2416 en_US
dc.description.abstract Recently, there have been several studies done regarding anion exchange membranes (AEMs) based on polyepichlorohydrin (PECH), an attractive polymer enabling safe membrane fabrication due to its inherent chloromethyl groups. However, there are still undiscovered properties of these membranes emerging from different compositions of cast solutions. Thus, it is vital to explore new membrane properties for sustainable energy generation by reverse electrodialysis (RED). In this study, the cast solution composition was easily tuned by varying the ratio of active polymer (i.e., blend ratio) and quaternary agent (i.e., excess diamine ratio) in the range of 1.07-2.00, and 1.00-4.00, respectively. The membrane synthesized with excess diamine ratio of 4.00 and blend ratio of 1.07 provided the best results in terms of ion exchange capacity, 3.47 mmol/g, with satisfactory conductive properties (area resistance: 2.4 omega center dot cm(2), electrical conductivity: 6.44 mS/cm) and high hydrophilicity. RED tests were performed by AEMs coupled with the commercially available Neosepta CMX cation exchange membrane (CEMs). en_US
dc.description.sponsorship TUBITAK [118M804] en_US
dc.description.sponsorship This research was funded by TUBITAK through Concert Japan project, grant number 118M804. en_US
dc.identifier.citationcount 3
dc.identifier.doi 10.3390/membranes12121192
dc.identifier.issn 2077-0375
dc.identifier.issue 12 en_US
dc.identifier.pmid 36557099
dc.identifier.scopus 2-s2.0-85144605846
dc.identifier.scopusquality Q3
dc.identifier.uri https://doi.org/10.3390/membranes12121192
dc.identifier.uri https://hdl.handle.net/20.500.14411/2416
dc.identifier.volume 12 en_US
dc.identifier.wos WOS:000904273900001
dc.institutionauthor Güler, Enver
dc.language.iso en en_US
dc.publisher Mdpi en_US
dc.relation.publicationcategory Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı en_US
dc.rights info:eu-repo/semantics/openAccess en_US
dc.scopus.citedbyCount 3
dc.subject salinity gradient en_US
dc.subject blue energy en_US
dc.subject reverse electrodialysis en_US
dc.subject anion exchange membrane en_US
dc.subject polyepichlorohydrin en_US
dc.title Further Development of Polyepichlorohydrin Based Anion Exchange Membranes for Reverse Electrodialysis by Tuning Cast Solution Properties en_US
dc.type Article en_US
dc.wos.citedbyCount 3
dspace.entity.type Publication
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