Browsing by Author "Konca,E."
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Article Citation Count: 24Effect of Electrodeposition Parameters on the Current Density of Hydrogen Evolution Reaction in Ni and Ni-Mos2 Composite Coatings(2013) Saralog̀lu Güler,E.; Konca, Erkan; Konca,E.; Karakaya,I.; Metallurgical and Materials EngineeringNickel composites with co-deposited insoluble, solid lubricant particles such as MoS2 have been reported to reduce friction. It is known that hydrogen evolution reaction (HER), competes with nickel deposition. The influence of the parameters and their interaction effects on the peak current density of HER during the electrodeposition of Ni and Ni-MoS2 composite coatings were studied by fractional factorial design. The parameters and their ranges studied were; MoS2 particle concentration (0-30 g/l), temperature (30-50°C), pH (2-4) and two surfactants, namely; ammoniumlignosulfonate (ALS) and depramin-C (DC) (0-1 g/l). Electrodeposition processes were carried out from a typical Watts bath containing leveler, wetting agent and brightener by using a potentiostat. The peak current densities (ip) were extended to higher values and the peaks onlinear sweep voltammograms became noticeable by increasing the scan rate from 20 mV/s to 100 mV/s over the range of 0 to 2.5 V. The peak current densities (ip) of HER for each experimental route were determined by fractional factorial design for two mineral processing surfactants; ammoniumlignosulfonate (ALS) and depramin-C (DC) using a statistical analysis software named Minitab [1]. Adding MoS2, decreasing temperature and increasing pH had decreasing effects on the peak current density of HER regardless of the surfactant used. On the other hand, the surfactants increased the peak current density. © 2013 by ESG.Conference Object Citation Count: 0Effect of Electroplating Parameters on "her" Current Density in Ni-Mos2 Composite Plating(Minerals, Metals and Materials Society, 2012) Güler,E.S.; Konca, Erkan; Karakaya,I.; Konca,E.; Metallurgical and Materials EngineeringNickel composites with co-deposited insoluble, solid lubricant particles such as MoS2 have been reported to reduce friction. It is known that hydrogen evolution reaction (HER), competes with nickel deposition. The influence of the electroplating parameters and their interaction effects on the peak current density for HER were studied by fractional factorial design. The parameters and their ranges were; MoS2 concentration (0-30 g/l), temperature (30-50°C), pH (2-4) and surfactants (0-1 g/l). Electrodeposition processes were carried out from a typical Watts bath containing leveler, wetting agent and brightener by using a potentiostat. The peak currents (I p) were extended to higher values and the peaks on linear sweep voltammograms became noticeable by increasing the scan rate from 20 mV/s to 100 mV/s over the range 0 to 2.5 V. The peak current densities (ip) for each experimental route were determined by fractional factorial design for three types of mineral processing surfactants; sodiumlignosulfonate (SLS), depramin-C (DC) and ammoniumlignosulfonate (ALS) using Minitab program [1]. Adding MoS2, decreasing temperature and increasing pH has decreasing effect on peak current density for all surfactants. ALS and DC have increasing effect whereas SLS has descending effect on peak current.Book Part Citation Count: 0Effect of Electroplating Parameters on Internal Stress in Ni-M0s2 Composite Plating(Wiley Blackwell, 2013) Güler,E.S.; Konca, Erkan; Konca,E.; Karakaya,I.; Metallurgical and Materials Engineering[No abstract available]Conference Object Citation Count: 1Effect of Electroplating Parameters on Internal Stress in Ni-Mos 2 Composite Plating(2013) Saraloǧlu Güler,E.; Konca, Erkan; Konca,E.; Karakaya,I.; Metallurgical and Materials Engineering[No abstract available]Article Citation Count: 17Investigation of the Tribological Behaviour of Electrocodeposited Ni-Mos2 Composite Coatings(Inderscience Publishers, 2017) Güler,E.S.; Konca, Erkan; Konca,E.; Karakaya,I.; Metallurgical and Materials EngineeringComposite electroplating of solid lubricants in a metal matrix is an effective way to lower coefficient of friction (COF) and improve wear resistance of surfaces in sliding contact. In this work, Ni-MoS2 composite coatings were deposited on AISI 304 stainless steel substrates by electroplating from Watts bath containing suspended MoS2 particles and their tribological behaviour was studied. The effects of MoS2 particle concentration (5, 10 and 30 g/l), MoS2 particle size (1.440 and 5.156 μm), pH (2, 3 and 4), current density (3.8, 4.8 and 5.8 A/dm2) and the surfactant (sodium lignosulfonate, SLS) concentration (0.3 and 1 g/l) on the tribological behaviour were investigated using a ball-on-disc tribometer at ambient conditions. Lower current density, smaller particle size and higher concentration of MoS2 decreased COF. While increasing the surfactant concentration decreased the COF, its friction lowering effect was much more pronounced at relatively lower concentrations of MoS2 in the electrolyte. Copyright © 2017 Inderscience Enterprises Ltd.